Composite Molybdenum Boride – Cobalt Chrome Non-Stick Coating

 

The Molybdenum Boride coating has good resistance to high temperature erosion and sliding wear.

Thermal shock resistance is fair. General corrosion and high temperature corrosion resistance are very good.

The HVAF MoB coating has excellent non-stick properties.

The coating is inert to molten metals (zinc, aluminum, etc.).

Stock Material: MoB-CoCr Powder, Agglomerated And Sintered
Nominal compositionwt.%
Molybdenum Boride base
Total boron 8.0-8.5
Cobalt 25-28
Chrome 13.5-15
Molybdenum Boride Coating Properties
FeatureS.I. UnitsU.S. Units
Apparent metallographic porosity <1.5%
Bond strength to carbon steel 70 MPa @ 500 microns 10,000 PSI @0.020″
Hardness 1000-1200 HV300
Typical as-sprayed roughness Ra: 2-3.2 µm 90-130 μin
Maximum coating thickness 750 microns 0.030”
Maximum working temperature 900°C 1,650°F
A Micrograph of an Anti-Stick HVAF Molybdenum Boride Coating

Molybdenum Boride Coating Characterization

The Molybdenum Boride coating has good resistance to high temperature erosion and sliding wear.

Thermal shock resistance is fair.

General corrosion and high temperature corrosion resistance are very good.

The HVAF MoB coating has excellent non-stick properties.

The coating is inert to molten metals (zinc, aluminum, etc.).

Typical Applications

Sliding wear and erosion at high temperatures, specifically for works related to oil well drilling;

non-stick coatings for a molten metals service (die-casting parts, galvanizing bath parts, sink rolls, etc.).

Non-stick Coatings For Hot Dipping Rolls
The Kermetico HVAF C7 Gun Spraying a MoB-CoCr Non-Stick Coating

MoB/CoCr cermet material with high durability in molten alloys has been developed for aluminum die-casting parts, and for hot continuous dipping rolls in Zn and Al-Zn plating lines, [Mizuno and Kitamura, 2007]. The tests revealed that a MoB/CoCr coating has high durability without dissolution in the molten Al-45wt.%Zn alloy. Using an undercoat is effective in reducing the effect of large differences in thermal expansion between the MoB/CoCr topcoat and substrate of stainless steel AISI 316L, widely used for hot continuous dipping.

MoB-based cermet powders (MoB/NiCr and MoB/CoCr) were deposited on SKD61 (AISI H-13) substrates used as a preferred die (mold) material [Khan et al 2011]. The durability of these coatings on cylindrical specimens against soldering has also been investigated by immersing them in molten aluminum alloy (ADC-12) for 25 hours at 670 °C.

Literature
  1. Khan F. F., G. Bae, K. Kang, H. Na, J. Kim, T. Jeong, and C. Lee, (2011) Evaluation of DieSoldering and Erosion Resistance of High Velocity Oxy-Fuel Sprayed MoB-Based Cermet Coatings, Journal of Thermal Spray Technology 20(5) 1022-1034
  2. Mizuno H. and Junya Kitamura, (2007) MoB/CoCr Cermet Coatings by HVOF Spraying against Erosion by Molten Al-Zn Alloy, Journal of Thermal Spray Technology 16(3) 404-413

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